Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite

被引：0
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作者：
D. A. Tatarinov
M. V. Kundina
A. B. Dobrynin
V. F. Mironov
机构：
[1] Russian Academy of Sciences,A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
[2] Kazan (Volga Region) Federal University,undefined
来源：
Russian Journal of General Chemistry | 2018年 / 88卷
关键词：
bis(trimethylsilyl) hypophosphite; mesityl oxide; methyl vinyl ketone; bis(3-oxobutyl)phosphinic acid; phosphorinane;
D O I：
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学科分类号：
摘要：
Bis(trimethylsilyl) hypophosphite reacts with unsaturated ketones (methyl vinyl ketone and mesityl oxide) to give, depending on the reaction conditions, 1: 1 or 1: 2 adducts after hydrolysis. It was found that the intramolecular cyclization of the 1: 2 reaction product with mesityl oxide, trimethylsilyl bis(2-methyl-4- oxopentan-2-yl)phosphinate, yields, after hydrolysis, a phosphorinane with exocyclic carbonyl and hydroxyl groups.
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页码：90 / 95
页数：5
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