Oxidation of benzylic alcohols to their Corresponding carbonyl compounds using ceric ammonium nitrate (CAN)/Brönsted acidic ionic liquid

被引:0
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作者
A. R. Hajipour
L. Khazdooz
A. E. Ruoho
机构
[1] University of Wisconsin,Department of Pharmacology
[2] Medical School,Pharmaceutical Research Laboratory, College of Chemistry
[3] Isfahan University of Technology,undefined
关键词
Oxidation; Alcohols; Ceric ammonium nitrate; Brönsted acidic ionic liquid;
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摘要
A chemoselective and efficient procedure for the oxidation of alcohols to the corresponding carbonyl compounds is reported using ceric ammonium nitrate in the presence of 3-methylimidazolium hydrogensulfate as Brönsted acidic ionic liquid ([Hmim]HSO4) as the solvent under mild conditions. The use of non-toxic and inexpensive materials, straightforward procedure, short reaction times and good yields of the products are the major advantages of this method.
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页码:382 / 387
页数:5
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