A new supramolecular compound based on Mn(II)-Schiff-base and Keggin-type [PMo12O40]3−

被引：0
|
作者：
M. L. Wei
P. F. Zhuang
R. P. Sun
H. H. Li
机构：
[1] Henan Normal University,College of Chemistry and Environmental Science
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Coordination Chemistry; Imidazole Ring; Methanol Molecule; Keggin Structure; Supramolecular Compound;
D O I：
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中图分类号：
学科分类号：
摘要：
A new organometallic-inorganic hybrid compound {[Mn(L)2]2[PMo12O40][NO3] · 4CH3OH · 3H2O}n (I), where L is 1,4-bis(4-imidazolyl)-2,3-diaza-1,3-butadiene) was synthesized in situ from [PMo12O40]3−, Mn2+ and L reaction in an H2O-DMSO-CH3OH mixture at room temperature, and the product was structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound I is constructed from alternating layers of the metal-Schiff-base cation and Keggin anions based on electrostatic forces and hydrogen bond interactions.
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页码：30 / 35
页数：5
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