Thermodynamic properties of spinel MgAl2O4: A mass spectrometric study

被引：0
|
作者：
S. I. Shornikov
机构：
[1] Russian Academy of Sciences,Vernadskii Institute of Geochemistry and Analytical Chemistry
来源：
Russian Journal of Physical Chemistry A | 2017年 / 91卷
关键词：
Knudsen effusion mass spectrometry; thermodynamic properties of spinel;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The activities of oxides in stoichiometric spinel MgAl2O4 in the temperature range 1851–2298 K were determined from the data obtained by the Knudsen effusion mass spectrometry. The resulting Gibbs energies of spinel formation from simple oxides, the enthalpies and entropies of spinel formation from simple oxides (–12.02 ± 1.14 kJ/mol and 5.03 ± 0.56 J/(mol K), respectively), and the spinel melting enthalpy (55.81 ± 4.62 kJ/mol) satisfactorily agree with the available thermodynamic data.
引用
收藏
页码：287 / 294
页数：7
相关论文
共 50 条
  • [1] Thermodynamic Properties of Spinel MgAl2O4: A Mass Spectrometric Study
    Shornikov, S. I.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (02) : 287 - 294
  • [2] Mass spectrometric study of the evaporation of MgAl2O4 spinel
    S. I. Shornikov
    Russian Journal of Physical Chemistry A, 2017, 91 : 10 - 16
  • [3] Mass spectrometric study of the evaporation of MgAl2O4 spinel
    Shornikov, S. I.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (01) : 10 - 16
  • [4] PALLADIUM OXIDE EQUILIBRATION AND THE THERMODYNAMIC PROPERTIES OF MGAL2O4 SPINEL
    CHAMBERLIN, L
    BECKETT, JR
    STOLPER, E
    AMERICAN MINERALOGIST, 1995, 80 (3-4) : 285 - 296
  • [5] Thermodynamic Properties of MgAl2O4 Spinel at High Temperatures and High Pressures
    Qiu, Wuxueying
    Su, Chang
    Liu, Yonggang
    Song, Wei
    CRYSTALS, 2023, 13 (02)
  • [6] Harmonic and anharmonic properties of spinel MgAl2O4
    Suzuki, I
    Ohno, I
    Anderson, OL
    AMERICAN MINERALOGIST, 2000, 85 (02) : 304 - 311
  • [7] Influence of the synthesis route on MgAl2O4 spinel properties
    Schreyeck, L
    Wlosik, A
    Fuzellier, H
    JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (02) : 483 - 486
  • [8] Vibrational and elastic properties of aluminate spinel MgAl2O4
    Kushwaha, A. K.
    PHYSICA B-CONDENSED MATTER, 2010, 405 (13) : 2795 - 2798
  • [9] REACTION OF MGAL2O4 SPINEL WITH CARBON
    VODOPYANOV, AG
    BARANOV, SV
    KOZHEVNIKOV, GN
    INORGANIC MATERIALS, 1983, 19 (10) : 1513 - 1515
  • [10] Defect processes in MgAl2O4 spinel
    Ball, J. A.
    Murphy, S. T.
    Grimes, R. W.
    Bacorisen, D.
    Smith, R.
    Uberuaga, B. P.
    Sickafus, K. E.
    SOLID STATE SCIENCES, 2008, 10 (06) : 717 - 724
12345