Synthesis, structure and nonlinear optical properties of two novel two-photon absorption chromophores

被引：0
|
作者：
LeHua Cheng
Lin Li
PingPing Sun
HongPing Zhou
YuPeng Tian
HuoHong Tang
机构：
[1] Anhui University,Department of Chemistry, Key Laboratory Functional Inorganic Materials of Anhui Province
[2] Chaohu College,Department of Chemistry
[3] University of Science and Technology of China,Department of Precision Machinery and Precision Instrumentation
来源：
Science in China Series B: Chemistry | 2009年 / 52卷
关键词：
two-photon absorption; triphenylamine derivative; chromophore; crystal structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore, tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine (1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine (2) were successfully synthesized and fully characterized by elemental analysis, IR, 1H NMR and MS. The single crystal X-ray diffraction analysis showed that the molecules possess D-(π-A)3 structures. One-and two-photon absorption and fluorescence in various solvents were experimentally investigated. A data recording experiment proved the potential application of these chromophores.
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页码：529 / 534
页数：5
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