The formation of petroleum biomarker hydrocarbons from possible oxygen-containing precursors

被引：0
|
作者：
T. V. Okunova
M. V. Giruts
O. G. Erdnieva
V. N. Koshelev
G. N. Gordadze
机构：
[1] Gubkin Oil and Gas State University,
[2] Kalmykian State University,undefined
来源：
Petroleum Chemistry | 2009年 / 49卷
关键词：
Thermolysis; Petroleum Hydrocarbon; Petroleum Chemistry; Mass Chromatogram; Thermolysis Product;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Some possible oxygen-containing precursors of petroleum hydrocarbons were subjected to mild thermolysis. It has been first shown that n-alkylcyclohexanes and steranes are formed along with the expected hydrocarbons n-alkanes and isoprenanes, which result from the loss of a functional group, and there is good correlation between the molecular-mass distributions of n-alkanes and n-alkylcyclohexanes. It has been found experimentally that sterane fragments of oxygen-containing compounds are thermodynamically unstable, and this is confirmed by the formation of biological C27–C29 5α,14α,17α,20S- and 20R-, and 5β,14α,17α,20R-(coprostane) steranes as a result of thermolysis.
引用
收藏
页码：207 / 217
页数：10
相关论文
共 50 条
  • [1] The formation of petroleum biomarker hydrocarbons from possible oxygen-containing precursors
    Okunova, T. V.
    Giruts, M. V.
    Erdnieva, O. G.
    Koshelev, V. N.
    Gordadze, G. N.
    [J]. PETROLEUM CHEMISTRY, 2009, 49 (03) : 207 - 217
  • [2] Comparative characterization of the distribution of biomarker hydrocarbons in the chemical transformation products of oxygen-containing precursors of petroleum
    T. V. Okunova
    M. V. Giruts
    O. G. Erdnieva
    V. N. Koshelev
    G. N. Gordadze
    [J]. Solid Fuel Chemistry, 2010, 44 : 351 - 363
  • [3] Comparative Characterization of the Distribution of Biomarker Hydrocarbons in the Chemical Transformation Products of Oxygen-Containing Precursors of Petroleum
    Okunova, T. V.
    Giruts, M. V.
    Erdnieva, O. G.
    Koshelev, V. N.
    Gordadze, G. N.
    [J]. SOLID FUEL CHEMISTRY, 2010, 44 (05) : 351 - 363
  • [4] Generation of C11-C17 Monoalkyladamantanes via Catalysis of Some Oxygen-Containing Precursors of Petroleum Hydrocarbons
    Badmaev, Ch M.
    Giruts, M. V.
    Erdnieva, O. G.
    Koshelev, V. N.
    Gordadze, G. N.
    [J]. PETROLEUM CHEMISTRY, 2011, 51 (05) : 331 - 335
  • [5] Generation of C11–C17 monoalkyladamantanes via catalysis of some oxygen-containing precursors of petroleum hydrocarbons
    Ch. M. Badmaev
    M. V. Giruts
    O. G. Erdnieva
    V. N. Koshelev
    G. N. Gordadze
    [J]. Petroleum Chemistry, 2011, 51 : 331 - 335
  • [6] SUCCESSFUL DIRECT FLUORINATION OF OXYGEN-CONTAINING HYDROCARBONS
    ADCOCK, JL
    BEH, RA
    LAGOW, RJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (22): : 3271 - 3275
  • [7] The synthesis of novel oxygen-containing ligands derived from amine precursors
    deKoning, CB
    Hancock, RD
    vanOtterlo, WAL
    [J]. TETRAHEDRON LETTERS, 1997, 38 (07) : 1261 - 1264
  • [8] Formation of Petroleum Hydrocarbons from Prokaryote Biomass: 1. Formation of Petroleum Biomarker Hydrocarbons from Thermoplasma sp Archaea Biomass
    Gordadze, G. N.
    Poshibaeva, A. R.
    Giruts, M. V.
    Perevalova, A. A.
    Koshelev, V. N.
    [J]. PETROLEUM CHEMISTRY, 2018, 58 (03) : 186 - 189
  • [9] Formation of Petroleum Hydrocarbons from Prokaryote Biomass: 1. Formation of Petroleum Biomarker Hydrocarbons from Thermoplasma sp. Archaea Biomass
    G. N. Gordadze
    A. R. Poshibaeva
    M. V. Giruts
    A. A. Perevalova
    V. N. Koshelev
    [J]. Petroleum Chemistry, 2018, 58 : 186 - 189
  • [10] PLASMA-CATALYTIC REFORMING OF OXYGEN-CONTAINING HYDROCARBONS
    Fedirchyk, I.
    Nedybaliuk, O.
    Chernyak, V.
    Demchina, V.
    [J]. HAKONE XV: INTERNATIONAL SYMPOSIUM ON HIGH PRESSURE LOW TEMPERATURE PLASMA CHEMISTRY: WITH JOINT COST TD1208 WORKSHOP: NON-EQUILIBRIUM PLASMAS WITH LIQUIDS FOR WATER AND SURFACE TREATMENT, 2016, : 177 - 179
12345