Synthesis, Spectroscopic Characterization and Structures of Tributyltin(IV) 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates. Toxicity Studies on the Second Larval Instar of the Anopheles stephensi Mosquito Larvae

被引：0

作者：

Tushar S. Basu Baul

Pradip Das

Eleonora Rivarola

Xueqing Song

George Eng

机构：

[1] North-Eastern Hill University,Department of Chemistry

[2] Dipartimento di Chimica Inorganica e Analitica “Stanislao Cannizzaro” Università degli Studi di Palermo,Department of Chemistry and Physics

[3] University of the District of Columbia,undefined

来源：

Journal of Inorganic and Organometallic Polymers and Materials | 2010年 / 20卷

关键词：

Organotin; Tributyltins; Carboxylates; 4-[((; )-1-{2-hydroxy-5-[(; )-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoic acids; Spectroscopy; Crystal structure; mosquito larvae;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A series of tributyltin(IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates have been investigated by 1H, 13C, 119Sn NMR, IR and 119Sn Mössbauer spectroscopic techniques in combination with elemental analyses. Single crystal X-ray crystallography of Bu3Sn[O2CC6H4{N=C(H)C6H3-2-OH(N=NC6H4CH3-4)}-p] reveals a distorted tetrahedral structure which is further supported by 119Sn Mössbauer data. Toxicity studies of the tributyltin(IV) complexes along with their ligands 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoic acids on the second larval instar of the Anopheles stephensi mosquito larvae are also reported.

引用

页码：61 / 68

页数：7

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