Liquid-phase oxidation of benzene and phenol on MCM-41 mesoporous molecular sieves modified with iron and cobalt compounds

被引：0
|
作者：
S. V. Sirotin
I. F. Moskovskaya
机构：
[1] Moscow State University,Faculty of Chemistry
来源：
Petroleum Chemistry | 2009年 / 49卷
关键词：
Acac; Cobalt Oxide; Petroleum Chemistry; FePc; Metal Introduction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nanostructured (I) Fe2O3 and Co3O4 stabilized in the mesopores of an MCM-41 sieve and immobilized (II) FeCl2, Fe(acac)3, and FePc on the surface of an MCM-41 sieve functionalized with 3-aminopropyltriethoxysilane (3-APTES) were synthesized and examined. The materials were characterized by elemental analysis, H2 -TPR, X-ray diffraction analysis, IR and electronic absorption spectroscopy, as well as by low-temperature N2 adsorption. The catalytic activity was evaluated in the reaction of liquid-phase oxidation of benzene and phenol with hydrogen peroxide. Catalysts I showed a low activity in benzene oxidation, whereas catalysts II were active in the oxidation of phenol.
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页码：99 / 105
页数：6
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