Highly dispersed Pt nanoparticles have been confined in the mesochannels of SBA-15 silica by a simple “one-pot” co-assembly method. Metallic Pt can be encapsulated in the mesochannels by changing the amount of Pt ions in the starting materials. The catalytic performances of Pt–SBA-15 were evaluated for methylcyclohexane dehydrogenation. Compared with conventional supported Pt–SiO2 catalysts, the Pt–SBA-15 catalysts show higher stability. TEM studies show that the confinement effect of ordered mesochannels of SBA-15 may restrict the further growth of Pt nanoparticles during the reaction.
机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Zhu, J
Kónya, Z
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Kónya, Z
Puntes, VF
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Puntes, VF
Kiricsi, I
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Kiricsi, I
Miao, CX
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Miao, CX
Ager, JW
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Ager, JW
Alivisatos, AP
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Alivisatos, AP
Somorjai, GA
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Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
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Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, IndiaStockholm Univ, Arrhenius Lab, Dept Phys Inorgan & Struct Chem, Mat Chem Res Grp, SE-10691 Stockholm, Sweden
Prashar, Atul K.
Hodgkins, Robert P.
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Stockholm Univ, Arrhenius Lab, Dept Phys Inorgan & Struct Chem, Mat Chem Res Grp, SE-10691 Stockholm, SwedenStockholm Univ, Arrhenius Lab, Dept Phys Inorgan & Struct Chem, Mat Chem Res Grp, SE-10691 Stockholm, Sweden
Hodgkins, Robert P.
Kumar, Rajiv
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Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, IndiaStockholm Univ, Arrhenius Lab, Dept Phys Inorgan & Struct Chem, Mat Chem Res Grp, SE-10691 Stockholm, Sweden
Kumar, Rajiv
Devi, R. Nandini
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Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, IndiaStockholm Univ, Arrhenius Lab, Dept Phys Inorgan & Struct Chem, Mat Chem Res Grp, SE-10691 Stockholm, Sweden