Synthesis and spectral parameters of symmetric and unsymmetrical sandwich-like double- and triple-decker lanthanide complexes containing 1-methyltetrabenzooctadehydrocorrin and phthalocyanine fragments

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作者
N. E. Galanin
L. A. Yakubov
G. P. Shaposhnikov
机构
[1] Ivanovo State University of Chemical Technology,
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关键词
Toluene; Phthalocyanine; Erbium; Electronic Absorption Spectrum; Hydrazine Hydrate;
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摘要
Single- and double-decker lanthanide complexes with 1-methyltetrabenzooctadehydrocorrin were synthesized by reaction of 3-[(1-hydroxy-1-methyl-1H-isoindol-3-yl)methylidene]-2,3-dihydro-1H-isoindol-1-one with hydrazine hydrate in the presence of lanthanide acetates. Heating of the former with phthalonitrile gave unsymmetrical double- and triple-decker complexes containing 1-methyltetrabenzooctadehydrocorrin and phthalocyanine fragments. Spectral properties of the synthesized complexes were studied.
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页码:941 / 947
页数:6
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