p-tert-butylcalix[4]arenes containing azacrown ether substituents at the lower rim as potential polytopic receptors

被引：0
|
作者：
E. A. Alekseeva
S. S. Basok
A. V. Mazepa
A. P. Luk’yanenko
O. V. Snurnikova
A. I. Gren’
机构：
[1] National Academy of Sciences of Ukraine,Bogatskii Institute of Physical Chemistry
来源：
Russian Journal of General Chemistry | 2013年 / 83卷
关键词：
Azacrown Ether; Calixarene Derivative; Metal Picrate; Complex Stability Constant; Ether Substituent;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of disubstituted p-tert-butylcalix[4]arenes with N-methoxycarbonylmonoazacrown ether and N-ethoxymonoazacrown ether residues at the lower rim has been prepared via the reaction of di(carboxymethoxy)-p-tert-butylcalix[4]arene with azacrown ethers and subsequent reduction of the resulting amide derivatives. Using UV titration and 1H NMR spectroscopy we have demonstrated the ability of the calixarene with two N-carbonylmonoaza-18-crown-6-ether substituents to form the 1:3 complexes with K+ and Na+ and the 1:2 complexes with Cs+, Sr2+, Cu2+, and Zn2+. The calixarene with two fragments of N-ethoxymonoazo-18-crown ether has formed binuclear complexes with alkali metals cations and mononuclear complexes with transition metals cations.
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页码：1738 / 1743
页数：5
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