Selective NO reduction by propane over commercial oxide catalysts and their mechanical mixture: I. Synergistic effect

被引：0
|
作者：
V. F. Tret’yakov
T. N. Burdeinaya
V. A. Matyshak
A. A. Ukharskii
O. S. Mokrushin
L. S. Glebov
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,Semenov Institute of Chemical Physics
[3] Gubkin State Academy of Oil and Gas,undefined
来源：
Kinetics and Catalysis | 2000年 / 41卷
关键词：
Reactive Flow; Mechanical Mixture; Commercial Catalyst; Reactant Conversion; Synergistic Property;
D O I：
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学科分类号：
摘要：
In the reaction of NO reduction by propane in excess oxygen, the activity of a binary mixture of commercial oxide catalysts is higher than should be expected if it were proportional to the activities of separate catalyst components. This synergism reveals itself in the fact that the conversion of NO and C3H8 is higher when the catalyst is a mechanical mixture than the sum of conversions over separate catalysts, all other conditions being the same. Based on the kinetic and thermal desorption measurements, the experimental conditions are found under which the synergism is observed. A hypothetical mechanism is proposed.
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页码：236 / 241
页数：5
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