Phase Identification of Cu-In Alloys with 45 and 41.25 at.% In Compositions

In this work, the thermal stability of Cu-In alloys with 45.0 and 41.2 at.% In nominal compositions was investigated by differential scanning calorimetry (DSC), scanning electron microscopy, wavelength dispersive spectroscopy, and in-situ synchrotron x-ray powder diffraction (S-PXRD) over a temperature range from 25 up to 400 °C. The studied samples are mainly composed of a Cu11In9 phase together with minor amounts of the B phase (based on the NiAs-Ni2In type structure) and, in one of the samples, with a minor amount of pure In. No evidence of the Cu10In7 (41.2 at.% In) phase was detected, not even in the sample with 41.2 at.% In nominal overall composition. The combined use of the S-PXRD and DSC techniques allowed us to identify two phase transitions involving the Cu11In9 phase, one of them corresponding to the η′⇌B+Cu11In9\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \upeta^{\prime} \rightleftharpoons {\text{B}} + {\text{Cu}}_{11} {\text{In}}_{9} $$\end{document} reaction at T = 290 °C and the other to the peritectic η′+L⇌Cu11In9\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \upeta^{\prime} + {\text{L}} \rightleftharpoons {\text{Cu}}_{11} {\text{In}}_{9} $$\end{document} reaction at T = 311 °C.