Evaluation of adiabatic runaway reaction and vent sizing for emergency relief from DSC

被引:0
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作者
Y. W. Wang
Y. S. Duh
C. M. Shu
机构
[1] National Yunlin University of Science and Technology,Doctoral Program of Engineering Science and Technology
[2] NYUST,Department of Occupational Safety and Health
[3] Jen-Teh Junior College of Medicine,Process Safety and Disaster Prevention Laboratory, Department of Safety, Health, and Environmental Engineering
[4] Nursing and Management,undefined
[5] National Yunlin University of Science and Technology,undefined
[6] NYUST,undefined
关键词
analytical equations; DSC; emergency relief behaviors; mass flow rates; vent sizing;
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学科分类号
摘要
Analytical equations related adiabatic runaway reactions to programmed scanning thermal curves from differential scanning calorimetry (DSC) were proposed. Thermal or pressure hazards can be assessed from the adiabatic trajectories expressed in the analytical equations. These industrially energetic materials include polymerizable monomers, unstable organic peroxides and nitro-compounds. Various emergency relief behaviors, such as tempered vapor, gassy, and hybrid were re-evaluated for calculating vent sizing or mass flow rates from DSC thermal curves and the related physical properties.
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页码:225 / 234
页数:9
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