Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O

被引：0
|
作者：
I. I. Seifullina
A. B. Ilyukhin
E. E. Martsinko
V. S. Sergienko
E. A. Chebanenko
机构：
[1] Mechnikov National University,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2015年 / 60卷
关键词：
Isoniazid; Organic Cation; Coordination Polyhedron; Crystallization Water Molecule; Germa Nium Dioxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Onium bis(citrate)germanates (HNad)2[Ge(HCit)2] · 4H2O (I), (HIm)2[Ge(HCit)2] · 2H2O (II), and (HInd)2[Ge(HCit)2] · 2H2O (III) (where Nad is nicotinamide, Im is imidazole, and Ind is isoniazid) were synthesized by the reaction between bis(citrate)hydroxogermanic(IV) acid (H5O2)[Ge(OH)(H2Cit)(H2.5Cit)]2 · 2CH3COOH · 2H2O (H4Cit is citric acid) and organic bases. The complexes were characterized by elemental analysis, thermogravimetry, and IR spectroscopy. The X-ray diffraction analysis of complex I was performed. The structural units of a crystal of complex I were found to be centrosymmetric complex [Ge(HCit)2]2− anions, HNad+ cations, and crystallization water molecules.
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页码：33 / 37
页数：4
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