Hierarchical percolation and electrical conduction of glasses in the 50WO3-(50 − x)P2O5-xNa2O system

被引：0
|
作者：
S. L. Kraevskii
V. F. Solinov
机构：
[1] Research Institute of Technical Glass,
来源：
Glass Physics and Chemistry | 2006年 / 32卷
关键词：
Ionic Conductivity; Glass Physic; Glass Phys; Percolation Problem; Percolation Parameter;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The validity of the proposed concept of hierarchical percolation is demonstrated using glasses in the WO3-P2O5-Na2O system as an example. The dependence of the electrical conductivity σ = σ0(ξ − ξcrit)μ (where ξ is the percolation parameter) with an exponent μ ≃ 1.4 close to the exponent theoretically predicted for two-dimensional percolation is obtained for the first time. This confirms our hypotheses regarding the two-dimensional percolation nature of electrical conduction over the surface of a phosphate cluster after the percolation threshold is overcome.
引用
收藏
页码：629 / 633
页数：4
相关论文
共 50 条
  • [1] Hierarchical Percolation and Electrical Conduction of Glasses in the 50WO3-(50-x)P2O5-xNa2O system
    Kraevskii, S. L.
    Solinov, V. F.
    GLASS PHYSICS AND CHEMISTRY, 2006, 32 (06) : 629 - 633
  • [2] STRUCTURE OF 50NA(2)O.XAL(2)O(3).(50-X)P2O5 AND (50-X/2)NA2O.XAL(2)O(3).(50-X/2)P2O5 GLASSES
    INOUE, H
    MAKISHIMA, A
    KANAZAWA, T
    NANBA, T
    YASUI, I
    PHYSICS AND CHEMISTRY OF GLASSES, 1995, 36 (01): : 37 - 43
  • [3] Chemical durability, electrical and dielectric properties of the ternary system (50-x)K2O-xMnO-50P2O5 phosphate glasses
    Ahmina, W.
    El Moudane, M.
    Shaim, A.
    Zriouil, M.
    Taibi, M.
    MATERIALS TODAY-PROCEEDINGS, 2019, 13 : 466 - 473
  • [4] Mixed alkali effect on crystallization kinetics of xNa2O:(50-x)Li2O:50P2O5
    Money, Benson K.
    Hariharan, K.
    SOLID STATE IONICS, 2014, 262 : 824 - 828
  • [5] Comparison of phosphate-based glasses in the range 50P2O5-(50-x)CaO-xNa2O prepared using different precursors
    Ahmed, I.
    Parsons, A. J.
    Rudd, C. D.
    Nazhat, S. N.
    Knowles, J. C.
    Guerry, P.
    Smith, M. E.
    GLASS TECHNOLOGY-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART A, 2008, 49 (02): : 63 - 72
  • [6] Synthesis, electrical conduction and structure-property correlation in (50-x) Ag2O-50P2O5-xCoCl2 glassy systems
    Das, S. S.
    Singh, N. P.
    Srivastava, Vibha
    Srivastava, P. K.
    SOLID STATE IONICS, 2008, 179 (40) : 2325 - 2329
  • [7] Density and FTIR analysis of 50Na2O-xCuO-(50-x)P2O5 glasses
    Chahine, A
    Et-Tabirou, M
    ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 2003, 28 (02): : 25 - 31
  • [8] Thermal properties, viscosities and densities of (50-x)Na2O-xCaO-50P2O5 glasses
    Shaharuddin, S. I. S.
    Ahmed, I.
    Furniss, D.
    Parsons, A. J.
    Rudd, C. D.
    GLASS TECHNOLOGY-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART A, 2012, 53 (06): : 245 - 251
  • [9] Electrical switching in the MoO3-WO3-P2O5 and MoO3-P2O5 glasses
    Hekmatshoar, M. H.
    Mirzayi, Mehdi
    Mirzayi, Mina
    IONICS, 2010, 16 (02) : 185 - 192
  • [10] Properties and structure of (50-x)BaO-xZnO-50P2O5 glasses
    Jung, BH
    Kim, DN
    Kim, HS
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2005, 351 (40-42) : 3356 - 3360
12345