Asymmetric photoredox transition-metal catalysis activated by visible light

被引：0
|
作者：
Haohua Huo
Xiaodong Shen
Chuanyong Wang
Lilu Zhang
Philipp Röse
Liang-An Chen
Klaus Harms
Michael Marsch
Gerhard Hilt
Eric Meggers
机构：
[1] Fachbereich Chemie,
[2] Philipps-Universität Marburg,undefined
[3] Hans-Meerwein-Straße,undefined
[4] 35043 Marburg,undefined
[5] Germany,undefined
[6] College of Chemistry and Chemical Engineering,undefined
[7] Xiamen University,undefined
[8] Xiamen 361005,undefined
[9] China,undefined
来源：
Nature | 2014年 / 515卷
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摘要：
A chiral iridium complex serves as a sensitizer for photoredox catalysis and at the same time provides very effective asymmetric induction for the enantioselective alkylation of 2-acyl imidazoles; the metal centre simultaneously serves as the exclusive source of chirality, the catalytically active Lewis acid centre, and the photoredox centre.
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页码：100 / 103
页数：3
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