Topochemical solid-state reactions and problems of selective synthesis of fullerene derivatives

被引：0
|
作者：
A. Ya. Borshchevskii
L. N. Sidorov
N. S. Chilingarov
V. E. Aleshina
机构：
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 2005年 / 54卷
关键词：
fluorofullerenes; solid-state fluorination; transition metal fluorides; activation energies;
D O I：
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中图分类号：
学科分类号：
摘要：
The characteristic features of polyaddition of small functional groups to fullerenes are considered. The review summarizes the results of experimental and theoretical studies of topochemical solid-state fluorination of fullerene C60 with inorganic variable-valence transition metal fluorides and elemental fluorine in chemically active matrices. The thermodynamic and kinetic aspects of the reactions and the factors responsible for selectivity are considered.
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页码：31 / 50
页数：19
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