Studies of a Model Mesh Electrode O2,Pt/O2- under Galvanostatic Polarization

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作者
S. N. Shkerin
机构
[1] Russian Academy of Sciences,Institute of High
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关键词
platinum electrode; YSZ single crystal; effect of face orientation and polarization;
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摘要
The impedance of model platinum mesh electrode in contact with a doped zirconium-dioxide-based single-crystal electrolyte is studied by impedance spectroscopy under constant-current polarization. The electrode is distinguished for its readily determinable geometrical characteristics of the metal/electrolyte interface, in particular, the length of the triple-phase boundary and the electrode contact area. Three different orientations of the electrolyte face are studied. The impedance dispersion is discussed in terms of the electrode prehistory, orientation, and potential.
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页码:510 / 515
页数:5
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