Transesterification and compatibilization in the blends of bisphenol-A polycarbonate and poly(trimethylene terephthalate)

被引:0
|
作者
Sang-Kuwon Na
Byeong-Gi Kong
Changyong Choi
Mi-Kyeong Jang
Jae-Woon Nah
Jung-Gyu Kim
Byung-Wook Jo
机构
[1] Sunchon National University,Department of Polymer Science and Engineering
[2] Chosun University,Chemical and Polymer Science & Engineering
来源
Macromolecular Research | 2005年 / 13卷
关键词
poly(trimethylene terephthalate); polycarbonate; blend; transesterification; compatibilization;
D O I
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中图分类号
学科分类号
摘要
Melt blending of Bisphenol A polycarbonate(PC) and poly(trimethylene terephthalate)(PTT) was carried out over the entire composition range. The mixing time was varied up to 90 min. The resulting samples were analyzed by FT-IR, DSC, XRD, DMTA,1H NMR, and SEM. The process of transesterification between the two polymers and their resulting compatibilization were observed. The behaviors of the PTT-rich and PC-rich blends were different and an equilibrium was found to exist. Peculiar behavior, which was different from that of the PTT-rich and PC-rich blends, was exhibited by the 50/50(PTT/PC) blend.
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页码:88 / 95
页数:7
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