Homo- and Heteronuclear Cobalt(III)-Based Complexes with 2-Methoxy-6-[(Methylimino)Methyl]Phenol: Structure and Antioxidant Properties

被引：0
|
作者：
V. N. Kokozay
E. V. Polunkin
O. Yu. Vassilyeva
T. M. Kameneva
V. S. Pilyavskiy
B. W. Skelton
机构：
[1] Taras Shevchenko National University of Kyiv,
[2] V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of NAS of Ukraine,undefined
[3] University of Western Australia,undefined
来源：
Theoretical and Experimental Chemistry | 2022年 / 58卷
关键词：
Schiff base; Co(III) complex; Co/Cd complex; Co/Mn complex; X-ray structural study; benzyl alcohol oxidation; inhibitor;
D O I：
暂无
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学科分类号：
摘要：
CoL3·DMF, [CoCdCl2L3]·0.5H2O, and [CoMnCl2L3]·H2O complexes, where HL is a product of the condensation of o-vanillin and methylamine have been obtained. The crystal structure of the latter complex has been determined by X-ray structural analysis. The study of the antioxidant activity of these complexes in a model reaction of radical-chain oxidation of benzyl alcohol with an atmospheric oxygen has proved a significant inhibition of this process at concentrations of the complexes of 10–7-10–6 mol/L. It is established that the inhibitory activity of the compounds depends on the nature of the metal ions present in the complex.
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页码：213 / 219
页数：6
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