Mechanism of thermal decomposition of yttrium nitrate hexahydrate, Y(NO3)3·6H2O and modeling of intermediate oxynitrates

被引：0
|
作者：
P. Melnikov
V. A. Nascimento
L. Z. Z. Consolo
A. F. Silva
机构：
[1] School of Medicine/UFMS,
来源：
Journal of Thermal Analysis and Calorimetry | 2013年 / 111卷
关键词：
Rare earth; Yttrium nitrate hexahydrate; Thermal decomposition; Oxynitrates; Computer modeling;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The thermal decomposition of yttrium nitrate hexahydrate Y(NO3)3·6H2O is a complex condensation process generating a tetramer arrangement Y4O4(NO3)4 formed by alternating yttrium and oxygen atoms. The anions NO3− attach themselves to the yttrium atoms. The tetramer gradually loses N2O5 and, through the formation of Y4O5(NO3)2, is transformed into yttrium oxide. The bond lengths and bond angles of intermediate oxynitrates calculated using the molecular mechanics method rendered data compatible with the results of X-ray diffraction for related compounds.
引用
收藏
页码：115 / 119
页数：4
相关论文
共 50 条
  • [1] Mechanism of thermal decomposition of yttrium nitrate hexahydrate, Y(NO3)3•6H2O and modeling of intermediate oxynitrates
    Melnikov, P.
    Nascimento, V. A.
    Consolo, L. Z. Z.
    Silva, A. F.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 111 (01) : 115 - 119
  • [2] Thermolysis mechanism of dysprosium hexahydrate nitrate Dy(NO3)3•6H2O and modeling of intermediate decomposition products
    Melnikov, P.
    Arkhangelsky, I. V.
    Nascimento, V. A.
    Silva, A. F.
    de Oliveira, L. C. S.
    Zanoni Consolo, L. Z.
    Herrero, A. S.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2015, 122 (02) : 571 - 578
  • [3] Thermolysis mechanism of dysprosium hexahydrate nitrate Dy(NO3)3·6H2O and modeling of intermediate decomposition products
    P. Melnikov
    I. V. Arkhangelsky
    V. A. Nascimento
    A. F. Silva
    L. C. S. de Oliveira
    L. Z. Zanoni Consolo
    A. S. Herrero
    [J]. Journal of Thermal Analysis and Calorimetry, 2015, 122 : 571 - 578
  • [4] Thermal decomposition of praseodymium nitrate hexahydrate Pr(NO3)3•6H2O
    Melnikov, P.
    Arkhangelsky, I. V.
    Nascimento, V. A.
    de Oliveira, L. C. S.
    Rodrigues Guimaraes, W.
    Zanoni, L. Z.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 133 (02) : 929 - 934
  • [5] Thermal decomposition of praseodymium nitrate hexahydrate Pr(NO3)3·6H2O
    P. Melnikov
    I. V. Arkhangelsky
    V. A. Nascimento
    L. C. S. de Oliveira
    W. Rodrigues Guimarães
    L. Z. Zanoni
    [J]. Journal of Thermal Analysis and Calorimetry, 2018, 133 : 929 - 934
  • [6] Thermal properties of europium nitrate hexahydrate Eu(NO3)3•6H2O
    Melnikov, P.
    Arkhangelsky, I. V.
    Nascimento, V. A.
    de Oliveira, L. C. S.
    Silva, A. F.
    Zanoni, L. Z.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2017, 128 (03) : 1353 - 1358
  • [7] Thermoanalytical behavior of neodymium nitrate hexahydrate Nd(NO3)3•6H2O
    Melnikov, P.
    Arkhangelsky, I. V.
    Nascimento, V. A.
    de Oliveira, L. C. S.
    Wandekoken, G. A.
    de Albuquerque, D. Muniz
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2020, 139 (06) : 3493 - 3497
  • [8] Thermoanalytical behavior of neodymium nitrate hexahydrate Nd(NO3)3·6H2O
    P. Melnikov
    I. V. Arkhangelsky
    V. A. Nascimento
    L. C. S. de Oliveira
    G. A. Wandekoken
    D. Muniz de Albuquerque
    [J]. Journal of Thermal Analysis and Calorimetry, 2020, 139 : 3493 - 3497
  • [9] Synthesis and crystal structure of two modifications of aluminum nitrate hexahydrate Al(NO3)3•6H2O
    Morozov, IV
    Marsova, MV
    Troyanov, SI
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (07) : 948 - 953
  • [10] Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2.6H2O in comparison to Co(NO3)2.6H2O and Ca(NO3)2.4H2O
    Brockner, Wolfgang
    Ehrhardt, Claus
    Gjikaj, Mimoza
    [J]. THERMOCHIMICA ACTA, 2007, 456 (01) : 64 - 68
12345