Metal-Cation-Directed Assembly of Two M–I (M = Cu, Ag) Clusters: Structures, Thermal Behaviors, Theoretical Studies, and Luminescence Properties

被引:0
|
作者
Wenjiang Huang
Hongyang Wei
Longhua Li
Jun Qian
Chi Zhang
机构
[1] Nanjing University of Science and Technology,Institute of Molecular Engineering and Advanced Materials, School of Chemical Engineering
[2] Jiangsu University,China
[3] Jiangnan University,Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy
来源
Journal of Cluster Science | 2016年 / 27卷
关键词
Clusters; Cation-directed assembly; Crystal structure; DFT calculations; Luminescence;
D O I
暂无
中图分类号
学科分类号
摘要
Two new M–I (M = Cu, Ag) clusters, {[Ce(DMF)8][Cu8I11]·C2H5OH}n (1) (DMF = dimethylfomamide) and {[Co(DMF)6]4[Ag7I11]2} (2), were synthesized with the direction of solvent-associated metal cations ([Ce(DMF)8]3+ in 1 and [Co(DMF)6]2+ for 2). Clusters 1 and 2 have been well-characterized by elemental analysis, infrared spectroscopy, ultraviolet/visible spectroscopies, single-crystal X-ray diffraction and thermogravimetric analysis. 1 contains the eight-coordinated cations [Ce(DMF)8]3+ and 1D polymeric anionic chain {[Cu8I11]3−}n, which is constructed from [Cu8I11]3− clusters connected with each other through µ3-I bridges and exhibits an interesting wavy chain structure. Cluster 2 consists of the six-coordinated cations [Co(DMF)6]2+ and the dimeric anionic cluster {[Ag7I11]2}8−, which is fabricated by a pair of heptanuclear butterfly-like clusters connected by two Ag–I bridges. Density functional theory (DFT) and time-dependent density functional theory (TD-DFT) calculations at the B3LYP/LanL2DZ*+6-31G* level were performed on clusters 1 and 2 to rationalize their experimental absorption spectra. Solid-state luminescence properties of clusters 1 and 2 have also been investigated at room temperature.
引用
收藏
页码:1463 / 1474
页数:11
相关论文
共 50 条
  • [1] Metal-Cation-Directed Assembly of Two M-I (M = Cu, Ag) Clusters: Structures, Thermal Behaviors, Theoretical Studies, and Luminescence Properties
    Huang, Wenjiang
    Wei, Hongyang
    Li, Longhua
    Qian, Jun
    Zhang, Chi
    JOURNAL OF CLUSTER SCIENCE, 2016, 27 (04) : 1463 - 1474
  • [2] Assembly of the heterometallic Au(I)-M(I) (M = Cu, Ag) clusters containing the dialkyne-derived diphosphines: synthesis, luminescence and theoretical studies
    Koshevoy, Igor O.
    Ostrova, Polina V.
    Karttunen, Antti J.
    Melnikov, Alexei S.
    Khodorkovskiy, Mikhail A.
    Haukka, Matti
    Janis, Janne
    Tunik, Sergey P.
    Pakkanen, Tapani A.
    DALTON TRANSACTIONS, 2010, 39 (38) : 9022 - 9031
  • [3] Metal-Cation-Directed Synthesis, Structures, and Optical Properties of Mo(W)/S(Se)/Ag Clusters: A Brief Overview
    Li, Jianghua
    Zhang, Jinfang
    Humphrey, Mark G.
    Zhang, Chi
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (03) : 328 - 346
  • [4] Metalloligand-induced Synthesis of Two Cu(I)-M (M=Ni, Co) Heterobimetallic Coordination Polymers: Structures, Thermal and Luminescence Properties
    Wei, Hongyang
    Huang, Wenjiang
    Qian, Jun
    Zhang, Chi
    JOURNAL OF CLUSTER SCIENCE, 2016, 27 (05) : 1537 - 1552
  • [5] Metalloligand-induced Synthesis of Two Cu(I)–M (M=Ni, Co) Heterobimetallic Coordination Polymers: Structures, Thermal and Luminescence Properties
    Hongyang Wei
    Wenjiang Huang
    Jun Qian
    Chi Zhang
    Journal of Cluster Science, 2016, 27 : 1537 - 1552
  • [6] Electronic structures and nonlinear optical properties of trinuclear transition metal clusters M-(μ-S)-M′ (M = Mo, W; M′ = Cu, Ag, Au)
    Chen, XH
    Wu, KC
    Snijders, JG
    Lin, CS
    INORGANIC CHEMISTRY, 2003, 42 (02) : 532 - 540
  • [7] Syntheses, structures, physical properties, and theoretical studies of CeMxOS (M = Cu, Ag; x ≈ 0.8) and CeAgOS
    Chan, George H.
    Deng, Bin
    Bertoni, Mariana
    Ireland, John R.
    Hersam, Mark C.
    Mason, Thomas O.
    Van Duyne, Richard P.
    Ibers, James A.
    INORGANIC CHEMISTRY, 2006, 45 (20) : 8264 - 8272
  • [8] Syntheses, structures and properties of two complexes bridged by [M(CN)2]- (M = Ag(I), Au(I))
    Liu, Mei-Ling
    Zhang, Li-Zhi
    Sun, Xiu-Ping
    Ma, Zhen-Ping
    Gu, Wen
    Liu, Xin
    JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (14) : 2266 - 2273
  • [9] Ligand-Assisted Conformation of Three Interesting Ni–M (M = Ag, Cu) Heterobimetallic Coordination Polymers: Syntheses, Structures, Thermal and Luminescence Properties
    Wenjiang Huang
    Hongyang Wei
    Jun Qian
    Chi Zhang
    Journal of Cluster Science, 2016, 27 : 1655 - 1669
  • [10] Structures and properties of M-S(M=Mo,W,Cu,Ag)clusters with TDT2- as ligands
    Lu, SF
    Yu, RM
    Huang, XY
    Wu, QJ
    Huang, JQ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U61 - U61