Sorption of Hexacyanoferrate(II, III) Anions on Nickel(II) Hydroxide

被引：0
|
作者：
O. V. Nagornyi
A. S. Kolyshkin
V. V. Vol'khin
机构：
[1] Perm State Technical University,
来源：
Russian Journal of Applied Chemistry | 2003年 / 76卷
关键词：
Spectroscopy; Potassium; Nickel; Aqueous Solution; Hydroxide;
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摘要：
Fe(CN)63- and Fe(CN)64- anions are sorbed from aqueous solutions of their potassium and cesium salts on β-Ni(OH)2 by the mechanism of anion exchange with hydroxy groups. Alkali metal cations (K+, Cs+) are also partly sorbed on nickel(II) hydroxide in the form of anionic complexes (K,Cs)zFe(CN)6(n - z)-, where n = 3 or 4 (0 < z < n). The chemical composition of the new phase appearing in contact of nickel(II) hydroxide with aqueous potassium and cesium hexacyanoferrates(II, III) was determined by X-ray phase analysis and IR spectroscopy.
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页码：1238 / 1241
页数：3
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