Calculation of thermodynamic properties of gold and silver complexes of mixed composition

被引：0
|
作者：
N. S. Bekturganov
D. B. Gogol’
M. R. Bisengalieva
A. S. Mukusheva
A. K. Koizhanova
L. L. Osipovskaya
机构：
[1] Parasat National Research and Technology Holding,
[2] Institute for the Problems of Complex Development of Mineral Resources,undefined
[3] Earth Science,undefined
[4] Metallurgy,undefined
[5] and Concentration Corporation,undefined
来源：
Russian Journal of Inorganic Chemistry | 2014年 / 59卷
关键词：
Potential Energy Surface; Hydration Energy; Gold Complex; Cyanide Complex; Silver Complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Computation for gold and silver complexes of mixed composition with cyanide, rhodanide, and thiosulfate anions was carried out by PM6 semiempirical method. Heats of formation in a gas phase and aqueous medium and hydration energies were determined for 224 possible structure variations. For 15 most stable structures, thermodynamic parameters of interaction with AM-2B anionite were determined: adsorption energies, energetically favorable configurations, activation energies, potential energy surfaces, etc.
引用
收藏
页码：337 / 344
页数：7
相关论文
共 50 条
  • [1] Calculation of thermodynamic properties of gold and silver complexes of mixed composition
    Bekturganov, N. S.
    Gogol', D. B.
    Bisengalieva, M. R.
    Mukusheva, A. S.
    Koizhanova, A. K.
    Osipovskaya, L. L.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 59 (04) : 337 - 344
  • [2] Calculation of Thermodynamic and Structural Characteristics of Gold and Silver Solvate Complexes
    A. K. Koizhanova
    B. K. Kenzhaliev
    M. R. Bisengalieva
    A. S. Mukusheva
    D. B. Gogol
    N. N. Abdyldaev
    D. R. Magomedov
    Russian Journal of Inorganic Chemistry, 2020, 65 : 1051 - 1060
  • [3] Calculation of Thermodynamic and Structural Characteristics of Gold and Silver Solvate Complexes
    Koizhanova, A. K.
    Kenzhaliev, B. K.
    Bisengalieva, M. R.
    Mukusheva, A. S.
    Gogol, D. B.
    Abdyldaev, N. N.
    Magomedov, D. R.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (07) : 1051 - 1060
  • [4] THE THERMODYNAMIC PROPERTIES OF SILVER-GOLD ALLOYS
    WHITE, JL
    ORR, RL
    HULTGREN, R
    ACTA METALLURGICA, 1957, 5 (12): : 747 - 760
  • [5] Thermodynamic properties of solid solutions of gold and silver
    Wachter, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1932, 54 : 4609 - 4617
  • [6] Calculation of optical properties of gold-silver alloys
    Morilova, LV
    Voloshinskiy, AN
    FIZIKA METALLOV I METALLOVEDENIE, 1997, 84 (04): : 22 - 34
  • [7] CALCULATION OF THERMODYNAMIC PROPERTIES OF SATURATED SOLUTIONS OF MIXED ELECTROLYTES
    WOOD, JR
    EUGSTER, HP
    HELGESON, HC
    TRANSACTIONS-AMERICAN GEOPHYSICAL UNION, 1972, 53 (04): : 531 - &
  • [8] Structural studies of lanthanide ion complexes of pure gold, pure silver and mixed metal (gold silver) dicyanides
    Colis, JCF
    Larochelle, C
    Staples, R
    Herbst-Irmer, R
    Patterson, H
    DALTON TRANSACTIONS, 2005, (04) : 675 - 679
  • [9] CALCULATION OF THE COMPOSITION AND STABILITY OF SILVER AMMINE COMPLEXES FROM SOLUBILITY DATA
    SETH, RL
    DEY, AK
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 17 (3-4): : 312 - 316
  • [10] COMPOSITION AND STABILITY OF MIXED SILVER(I) IODIDE-THIOCYANATE COMPLEXES
    PAILLIOTET, A
    GARATIN, F
    POURADIER, J
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1977, 285 (04): : 97 - 100
12345