Sulfide-conducting solid electrolytes for preparation of nonstoichiometric compounds with controlled composition and properties

被引:0
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作者
E. G. Fominykh
L. A. Kalinina
G. I. Shirokova
Yu. N. Ushakova
T. I. Rychkova
B. A. Ananchenko
机构
[1] Vyatka State University,
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关键词
Solid Electrolyte; Homogeneity Region; Electromotive Force; Glass Physic; Coulometric Titration;
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摘要
The influence of the electrolytic properties of the sulfide-conducting electrolytes CaY2S4, CaPr2S4, and BaSm2S4 on the possibility of performing the electrochemical correction of the composition of nonstoichiometric cadmium and lead sulfides is investigated. The width of the homogeneity region of the CdS and PbS sulfides is estimated in the temperature range 300–400°C. A model of defect formation is proposed.
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页码:362 / 368
页数:6
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