A Silicotungstate-Based Silver(I) Compound with Octanuclear Core: Synthesis, Crystal Structure and Luminescent Property

被引：0
|
作者：
Qin Guo
Cheng-Yuan Zhu
Yan-Li Gai
Yi Zhu
Wen-Yan Cai
Bing Liang
Wen-Shu Zhang
Ke-Cai Xiong
Qing-Fu Zhang
机构：
[1] Jiangsu Normal University,School of Chemistry and Materials Science
[2] Liaocheng University,College of Chemistry and Chemical Engineering
来源：
Journal of Cluster Science | 2019年 / 30卷
关键词：
Polyoxometalate; Silver(I)-based cluster; Crystal structure; Luminescence;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel silicotungstate-based silver(I) compound, formulated as [{Ag8(H3mtz)12}{SiW12O40}2]·8H2O (1) (H3mtz = 3-Mercapto-1,2,4-triazole) has been hydrothermally synthesized. This compound was identified by the single-crystal X-ray diffraction, and also characterized by FT-IR, UV, TG, PXRD and elemental analyses. The data show that it possesses the octanuclear silver(I) clusters and the anionic silicotungstates, which were connected via the hydrogen bonds and weak Ag–O bonds. Interestingly, the estimated optical bandgap of compound 1 is 1.95 eV, which falls into the range of semiconductors.
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页码：365 / 370
页数：5
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