High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis

被引:0
|
作者
Ming Joo Koh
R. Kashif M. Khan
Sebastian Torker
Miao Yu
Malte S. Mikus
Amir H. Hoveyda
机构
[1] Merkert Chemistry Center,Department of Chemistry
[2] Boston College,undefined
来源
Nature | 2015年 / 517卷
关键词
D O I
暂无
中图分类号
学科分类号
摘要
A ruthenium–disulfide catalyst is presented that is effective in generating compounds of medical and industrial utility (alcohols that contain a phenol, an aldehyde, or a carboxylic acid) by room-temperature, inexpensive, high-yielding cross-metathesis.
引用
收藏
页码:181 / 186
页数:5
相关论文
共 21 条
  • [1] High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis
    Koh, Ming Joo
    Khan, R. Kashif M.
    Torker, Sebastian
    Yu, Miao
    Mikus, Malte S.
    Hoveyda, Amir H.
    [J]. NATURE, 2015, 517 (7533) : 181 - 186
  • [2] Catalytic Z-selective olefin cross-metathesis for natural product synthesis
    Meek, Simon J.
    O'Brien, Robert V.
    Llaveria, Josep
    Schrock, Richard R.
    Hoveyda, Amir H.
    [J]. NATURE, 2011, 471 (7339) : 461 - 466
  • [3] Catalytic Z-selective olefin cross-metathesis for natural product synthesis
    Simon J. Meek
    Robert V. O’Brien
    Josep Llaveria
    Richard R. Schrock
    Amir H. Hoveyda
    [J]. Nature, 2011, 471 : 461 - 466
  • [4] Efficient and Z-selective cross-metathesis of conjugated enynes
    Hansen, EC
    Lee, D
    [J]. ORGANIC LETTERS, 2004, 6 (12) : 2035 - 2038
  • [5] Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1
    Speed, Alexander W. H.
    Mann, Tyler J.
    O'Brien, Robert V.
    Schrock, Richard R.
    Hoveyda, Amir H.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (46) : 16136 - 16139
  • [6] Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols
    Dornan, Peter K.
    Wickens, Zachary K.
    Grubbs, Robert H.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (24) : 7134 - 7138
  • [7] Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions and Z-Selective Ring-Opening Metathesis Polymerization
    Cordova, Armando
    Rios, Ramon
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) : 8827 - 8831
  • [8] Complete Stereocontrol in the Synthesis of Harmonine and Novel Analogues Facilitated by a Grubbs Z-Selective Cross-Metathesis Catalyst
    Abel, Steven-Alan G.
    Olivier, Wesley J.
    Pederson, Richard L.
    Bissember, Alex C.
    Smith, Jason A.
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2015, 68 (12) : 1815 - 1820
  • [9] Efficient Z-Selective Olefin-Acrylamide Cross-Metathesis Enabled by Sterically Demanding Cyclometalated Ruthenium Catalysts
    Xu, Yan
    Wong, Jonathan J.
    Samkian, Adrian E.
    Ko, Jeong Hoon
    Chen, Shuming
    Houk, K. N.
    Grubbs, Robert H.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (50) : 20987 - 20993
  • [10] Catalytic Z-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis
    Mann, Tyler J.
    Speed, Alexander W. H.
    Schrock, Richard R.
    Hoveyda, Amir H.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (32) : 8395 - 8400