Formation of Co nanoparticles in the process of thermal decomposition of the cobalt complex with hexamethylenetetramine (NO3)2Co(H2O)6(HMTA)2 · 4(H2O)

被引：0

作者：

P. A. Chernavskii

P. V. Afanas’ev

G. V. Pankina

N. S. Perov

机构：

[1] Moscow State University,Chemical Department

[2] Institut de Recherche sur la Catalyse,Physical Department

[3] Moscow State University,undefined

来源：

Russian Journal of Physical Chemistry A, Focus on Chemistry | 2008年 / 82卷

关键词：

Thermal Decomposition; Thermal Explosion; Thermal Destruction; Hexamethylenetetramine; HMTA;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The thermal decomposition of the cobalt complex with hexamethylenetetramine (NO3)2Co(H2O)6(HMTA)2 · 4(H2O) was studied by the methods of differential thermal analysis, thermogravimetry, mass spectrometry, X-ray diffraction analysis, and by the magnetic method. It was established that the thermal decomposition of the complex in a current of an inert gas is accompanied by a pronounced exothermic process and formation of Co nanoparticles. It was shown that the kinetics of this process and the chemical nature of the decomposition products depend on the initial density of the sample under study.

引用

页码：2176 / 2181

页数：5

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