A highly luminescent terbium-organic framework for reversible detection of mercury ions in aqueous solution

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作者
Hong-Ming Wang
Yang-Yi Yang
Cheng-Hui Zeng
Tian-Shu Chu
Yi-Min Zhu
Seik Weng Ng
机构
[1] Sun Yat-Sen University,MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering
[2] Guangdong University of Education,Department of Chemistry
[3] University of Malaya,Department of Chemistry
[4] King Abdulaziz University,Department of Chemistry, Faculty of Science
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摘要
A new organic-lanthanide framework [TbL1.5(H2O)2]·H2O (11) [H2L = 5-(3′-carboxylphenyl)nicotinic acid] was synthesized. Its structure was determined by single crystal X-ray diffraction. The complex was characterized by PXRD, FT-IR, fluorescence as well as TGA, and features a 3D framework with a 1D channel and exhibits exceptionally high thermal stability up to 440 °C in air. Furthermore, it displays highly sensitive and selective luminescence quenching to Hg2+ in aqueous solution. The result of a reversible sensing experiment showed complex 1 could be reusable at least 5 times.
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页码:1700 / 1706
页数:6
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