Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12

被引：0
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作者：
Jing-Mu Yang
Bin Hu
Chun-Gu Xia
机构：
[1] Chinese Academy of Sciences,State key laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics
[2] Graduate School of Chinese Academy of Sciences,undefined
来源：
Journal of Cluster Science | 2008年 / 19卷
关键词：
Trinuclear metal cluster; Fischer-type carbene; Thiocarboxamido ligand; Crystal structure;
D O I：
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学科分类号：
摘要：
Two new Fischer-type carbene-containing trinuclear transition-metal clusters: (μ3-S)Co3(CO)7[μ, η2-SCNEt2] 1 and CoRu2(CO)9[μ3, η2-SCNEt2] 2 were obtained by the reaction of tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12. These clusters contain thiocarboxamido ligand in different coordination modes. The thiocarboxamido ligand served as monometalated or dimetalated sulfur(diethy1amino) carbene ligand in these clusters. Clusters 1 and 2 were characterized by IR, 1H NMR, and single-crystal X-ray diffraction.
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页码：615 / 621
页数：6
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