Crystal Structure and Thermal Properties of a 2D Silver(I) Coordination Polymer with Semi-Rigid Bis(Pyrazole)

被引：0
|
作者：
J. Cheng
G.-H. Wang
Y.-W. Wang
机构：
[1] Hebei University of Environmental Engineering,Journal Editorial Department
来源：
Journal of Structural Chemistry | 2018年 / 59卷
关键词：
Ag(I) complex; bis(pyrazole); crystal structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
An Ag(I) coordination polymer [Ag2(L)2(H2btc)]n (L = 4,4′-bis(3,5-dimethylpyrazol-1-ylmethyl)-biphenyl, H4btc = 1,2,4,5-benzenetetracarboxylic acid) is hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TGA analysis, and single crystal X-ray diffraction. It crystallizes in the triclinic space group Pī, a = 10.670(8) Å, b = 10.990(8) Å, c = 23.697(2) Å, α = 81.847(10), β = 82.171(10), γ = 80.592(10)°, V = 2695.5(3) Å3, Z = 2, Dcalc = 1.489 g/cm3, μ = 0.789 mm–1. The title compound displays a uninodal three-connected hcb/Shubnikov hexagonal plane with {63} topology, which is further extended into a 3D supramolecular framework via C–H···O interactions.
引用
收藏
页码：729 / 732
页数：3
相关论文
共 50 条
  • [1] Crystal Structure and Thermal Properties of a 2D Silver(I) Coordination Polymer with Semi-Rigid Bis(Pyrazole)
    Cheng, J.
    Wang, G. -H.
    Wang, Y. -W.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (03) : 729 - 732
  • [2] Crystal structure and fluorescence of a 1D zinc(II) coordination polymer based on a semi-rigid bis(benzimidazole) ligand
    W.-L. Hou
    G.-Y. Dong
    X.-X. Wang
    K. Van Hecke
    [J]. Journal of Structural Chemistry, 2015, 56 : 1572 - 1576
  • [3] Crystal structure and fluorescence of a 1D zinc(II) coordination polymer based on a semi-rigid bis(benzimidazole) ligand
    Hou, W. -L.
    Dong, G. -Y.
    Wang, X. -X.
    Van Hecke, K.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (08) : 1572 - 1576
  • [4] Synthesis, Crystal Structure and Property of 2D Layer Structure Silver(I) Coordination Polymer
    Fang Xiang-Qian
    Zhu Zhi-Biao
    Deng Zhao-Peng
    Gao Shan
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (02) : 275 - 278
  • [5] Silver coordination networks and cages based on a semi-rigid bis(isoxazolyl) ligand
    Burrows, Andrew D.
    Kelly, David J.
    Mahon, Mary F.
    Raithby, Paul R.
    Richardson, Christopher
    Stevenson, Anna J.
    [J]. DALTON TRANSACTIONS, 2011, 40 (20) : 5483 - 5493
  • [6] Crystal structure and fluorescent properties of a 2D cadmium coordination polymer
    X. Du
    Y. Y. Wang
    Y. Q. Zhao
    G. H. Cui
    [J]. Journal of Structural Chemistry, 2014, 55 : 739 - 743
  • [7] Crystal structure and fluorescent properties of a 2D cadmium coordination polymer
    Du, X.
    Wang, Y. Y.
    Zhao, Y. Q.
    Cui, G. H.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (04) : 739 - 743
  • [8] Sonochemical synthesis of two nanostructured silver(I) coordination polymers based on semi-rigid bis(benzimidazole) ligands
    Hao, Shao Yun
    Li, Yue Hua
    Hao, Zeng Chuan
    Cui, Guang Hua
    [J]. ULTRASONICS SONOCHEMISTRY, 2017, 39 : 636 - 644
  • [9] Crystal Structure of a 1D Silver(I) Coordination Polymer Containing Flexible bis(benzimidazole)
    Cui, J. W.
    Wang, S. C.
    Wang, Y. Y.
    Dong, G. Y.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (01) : 227 - 230
  • [10] Crystal Structure of a 1D Silver(I) Coordination Polymer Containing Flexible bis(benzimidazole)
    J. W. Cui
    S. C. Wang
    Y. Y. Wang
    G. Y. Dong
    [J]. Journal of Structural Chemistry, 2018, 59 : 227 - 230
12345