Double clathrate hydrates of cross-linked tetrabutylammonium polyacrylate and noble gases at high pressures

被引:0
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作者
E. Ya. Aladko
E. G. Larionov
A. Yu. Manakov
I. S. Terekhova
机构
[1] Siberian Branch of the Russian Academy of Sciences,A.V. Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
关键词
Clathrate hydrate; Tetrabutylammonium polyacrylates; Noble gas; High pressure; Phase diagram;
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摘要
Temperatures of hydrate decomposition were measured by means of the differential thermal analysis at a pressures up to 800–900 Mpa in the systems: cross-linked tetrabutylammonium polyacrylate–water and cross-linked tetrabutylammonium polyacrylate–water–noble gas (He, Ne, Ar, Kr, Xe). The effect of the deformation of D- cavities of the hydrates on the temperature of their decomposition is discussed on the basis of the experimental data.
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页码:13 / 18
页数:5
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