Improvement of the efficiency of electrochemical refining of cobalt

被引:0
|
作者
F. D. Manilevich
L. F. Kozin
B. I. Danil’tsev
机构
[1] National Academy of Sciences of Ukraine,Vernadskii Institute of General and Inorganic Chemistry
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关键词
Cobalt; Anodic Dissolution; Impurity Metal; Cathode Chamber; Cathode Deposit;
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摘要
To improve the purity of cobalt produced by electrochemical refining, the optimal electrolyte composition and electrolysis mode were determined and a method for diminishing the electrochemical activity of impurity metals in anodic dissolution of the raw metal and a system for deep purification of the electrolyte solution to remove impurities were developed. Cathode deposits with a conditional cobalt content exceeding 99.999 wt %, found in an analysis for the 11 main impurities, were obtained by using the above results in refining of K1A cobalt (≥99.30 wt % Co) in an electrolyzer of distinctive design.
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页码:1333 / 1339
页数:6
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