Single-stage synthesis of phosphazene-containing epoxy oligomers

被引：0
|
作者：
I. S. Sirotin
Yu. V. Bilichenko
K. A. Brigadnov
V. V. Kireev
B. M. Prudskov
R. S. Borisov
机构：
[1] Mendeleev University of Chemical Technology,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,undefined
来源：
Polymer Science Series B | 2014年 / 56卷
关键词：
Polymer Science Series; Epichlorohydrin; Phosphazene; Epoxy Oligomer; Laser Mass Spectrometry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A single-stage synthesis of phosphazene-containing epoxy oligomers via the direct interaction of hexachlorocyclotriphosphazene, diphenylolpropane and epichlorohydrin has been proposed. The resulting products are composed of a common epoxy-diane oligomer and an epoxyphosphazene component, with the content of the latter being up to 45 wt %. Oligomers with epoxy numbers up to 22 were characterized with the use of gel permeation chromatography, chromatography-mass spectrometry, laser mass spectrometry, 31P NMR spectroscopy, and 1H NMR spectroscopy.
引用
收藏
页码：471 / 476
页数：5
相关论文
共 50 条
  • [1] Single-Stage Synthesis of Phosphazene-Containing Epoxy Oligomers
    Sirotin, I. S.
    Bilichenko, Yu. V.
    Brigadnov, K. A.
    Kireev, V. V.
    Prudskov, B. M.
    Borisov, R. S.
    [J]. POLYMER SCIENCE SERIES B, 2014, 56 (04) : 471 - 476
  • [2] Synthesis of Resorcinol-Based Phosphazene-Containing Epoxy Oligomers
    Sarychev, Igor A.
    Sirotin, Igor S.
    Borisov, Roman S.
    Mu, Jianxin
    Sokolskaya, Irina B.
    Bilichenko, Julya V.
    Filatov, Sergey N.
    Kireev, Vyacheslav V.
    [J]. POLYMERS, 2019, 11 (04)
  • [3] Rheological and rheokinetic properties of phosphazene-containing epoxy oligomers
    Simonov-Emel'yanov, I. D.
    Apeksimov, N. V.
    Kochergina, L. M.
    Bilichenko, Yu V.
    Kireev, V. V.
    Brigadnov, K. A.
    Sirotin, I. S.
    Filatov, S. N.
    [J]. POLYMER SCIENCE SERIES B, 2016, 58 (02) : 168 - 172
  • [4] Rheological and rheokinetic properties of phosphazene-containing epoxy oligomers
    I. D. Simonov-Emel’yanov
    N. V. Apeksimov
    L. M. Kochergina
    Yu. V. Bilichenko
    V. V. Kireev
    K. A. Brigadnov
    I. S. Sirotin
    S. N. Filatov
    [J]. Polymer Science Series B, 2016, 58 : 168 - 172
  • [5] Laser Mass Spectrometry Analysis of the Formation of Phosphazene-Containing Epoxy Oligomers
    Kireev, V. V.
    Bilichenko, Yu. V.
    Borisov, R. S.
    Sirotin, I. S.
    Filatov, S. N.
    [J]. POLYMER SCIENCE SERIES B, 2018, 60 (03) : 243 - 262
  • [6] Laser Mass Spectrometry Analysis of the Formation of Phosphazene-Containing Epoxy Oligomers
    V. V. Kireev
    Yu. V. Bilichenko
    R. S. Borisov
    I. S. Sirotin
    S. N. Filatov
    [J]. Polymer Science, Series B, 2018, 60 : 243 - 262
  • [7] SYNTHESIS OF PHOSPHAZENE-CONTAINING COPOLYESTERS
    ALEKSEENKO, LA
    MIKITAEV, AK
    SHUSTOV, GB
    KIREEV, VV
    [J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1978, 20 (03): : 176 - 177
  • [8] Synthesis of Bisphenol A Based Phosphazene-Containing Epoxy Resin with Reduced Viscosity
    Kireev, Vyacheslav V.
    Bilichenko, Yulya V.
    Borisov, Roman S.
    Mu, Jianxin
    Kuznetsov, Dmitry A.
    Eroshenko, Anastasiya V.
    Filatov, Sergey N.
    Sirotin, Igor S.
    [J]. POLYMERS, 2019, 11 (12)
  • [9] SYNTHESIS AND STUDY OF PHOSPHAZENE-CONTAINING POLYORGANOSILOXANES
    ASTRINA, VI
    KIREEV, VV
    SAVCHENKO, LA
    [J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1982, 24 (10): : 792 - 795
  • [10] Synthesis of a functionalised phosphazene-containing nanotube/epoxy nanocomposite with enhanced flame retardancy
    Zhao, Shishi
    He, Meng
    Xu, Jianzhong
    Ma, Haiyun
    [J]. MICRO & NANO LETTERS, 2017, 12 (06): : 401 - 403
12345