Thermodynamic regularities for associating fluids from statistical associating fluid theory equation of state

被引:0
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作者
A. Maghari
Z. Safaei
机构
[1] University College of Science,Department of Physical Chemistry
[2] University of Tehran,undefined
关键词
Equation of state; Isothermal bulk modulus; Statistical associating fluid theory; Tai-Murnaghan; Thermodynamic regularities;
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学科分类号
摘要
In this work, we used a statistical associating fluid theory to analyze two important thermodynamic regularities for some associating fluids, including water, methanol and ethanol. The studied regularities included: (i) the common bulk modulus point on the isotherms of the reduced bulk modulus versus reduced density, (ii) near linearity of the reduced isothermal bulk modulus as a function of reduced pressure. In this work, we also reported the influence of the molecular size and interaction strength on the bulk modulus point.
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页码:318 / 324
页数:6
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