Effect of the monomer concentration on piperylene cationic polymerization in the presence of the TiCl4-trichloroacetic acid catalytic system

被引：0
|
作者：
V. A. Rozentsvet
V. G. Kozlov
机构：
[1] Russian Academy of Sciences,Volga Basin Ecology Institute
来源：
Russian Chemical Bulletin | 2007年 / 56卷
关键词：
piperylene; cationic polymerization; kinetics; molecular parameters; branching;
D O I：
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学科分类号：
摘要：
The effect of the monomer concentration on the kinetics of cationic polymerization of piperylene in the presence of the TiCl4-trichloroacetic acid catalytic system and molecular weight of the produced polymer was studied. At high monomer concentrations, the high-molecular-weight peak related to the formation of the branched fraction appears in the molecular weight distribution curve of the produced polymer.
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页码：1359 / 1362
页数：3
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