Ionic liquid-based quasi-solid-state electrolyte for supercapacitor application

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作者
Hai Lu
Rui Feng
Peichun Wang
Yan Yuan
Zhiyun Zhang
Huiling Du
Xiangyuan Li
机构
[1] Xi’an University of Science and Technology,School of Materials Science and Engineering
[2] Xi’an University of Architecture and Technology,School of Metallurgical Engineering
[3] Xi’an Herong New Energy Technology Co.,undefined
[4] Ltd,undefined
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摘要
Quasi-solid-state electrolytes (QSSEs) via incorporating low-viscous ionic liquid (IL) into a copolymer matrix were fabricated for electric double-layer capacitors (EDLCs). It is found the IL amount brings about notable effects on the structure, physicochemical properties of the QSSE and electrochemical performance of the EDLC. The QSSE based on optimized polymer/IL mass ratio exhibits acceptable ionic conductivity, favorable thermal/structural stability and wide operation potential window. Consequently, the constructed EDLC yields a high gravimetric specific energy, rapid and reversible charge/discharge capability and outstanding capacitance retention over long-term cycling at the cut-off voltage of 3.0 V.
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页码:16828 / 16836
页数:8
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