Cobalt(II) complexes with 2-aminoacetophenone N(4)-substituted thiosemicarbazones

被引：0
|
作者：
Douglas X. West
Amal A. Nassar
Fathy A. El-Saied
Mohamed I. Ayad
机构：
[1] Illinois State University,Department of Chemistry
[2] El-Menoufia University,Department of Chemistry
来源：
Transition Metal Chemistry | 1999年 / 24卷
关键词：
Hydrogen; Nitrogen; Sulfur; Physical Chemistry; Cobalt;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Cobalt(II) complexes with 2-aminoacetophenone thiosemicarbazone and three N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r. and electronic spectra of the thiosemicarbazones and their complexes, along with physical properties of the complexes, have been obtained. The 2-aminoacetophenone thiosemicarbazones coordinate both as neutral and anionic ligands via the thiosemicarbazone moiety's imine nitrogen and thione/thiolato sulfur [on loss of the N(2) hydrogen].
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页码：617 / 621
页数：4
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