Influence of acid-base properties of oxides surface on their reactivity towards epoxy compounds

被引:0
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作者
P. A. Sitnikov
A. V. Kuchin
M. A. Ryazanov
A. G. Belykh
I. N. Vaseneva
M. S. Fedoseev
V. V. Tereshatov
机构
[1] Russian Academy of Sciences,Institute of Chemistry, Komi Scientific Center, Ural Branch
[2] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
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metal oxide; epoxide; polymer; reactive filler; equilibrium constant; homopolymerization;
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摘要
Acid-base properties of surface of aluminum, iron, and silicon oxides have been studied by pK spectroscopy. γ-Al2O3 and γ-AlO(OH) have been found the most reactive modifiers for epoxy oligomers, due to the presence of active surface groups with pK1 ≈ 4, capable of chemical interaction with the matrix.
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页码:810 / 815
页数:5
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