Adsorption of n-pentane on a microporous carbon adsorbent with a narrow pore size distribution

被引：0

作者：

A. V. Shkolin

A. A. Fomkin

V. A. Sinitsyn

机构：

[1] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry

来源：

Protection of Metals and Physical Chemistry of Surfaces | 2010年 / 46卷

关键词：

Narrow Pore Size Distribution; Microporous Carbon; Absolute Adsorption; Adsorption Isosteres; Microporous Carbon Adsorbent;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A model of thermochemical synthesis of a microporous carbon adsorbent of silicon carbide is developed. Isotherms of absolute adsorption of n-pentane on an AUK microporous carbon adsorbent of SiC with a narrow pore size distribution are measured in the pressure range of 1 Pa to 50 kPa and in the temperature interval of 243–393 K. The parameters of adsorption equilibrium of the adsorption isostere calculated in the same range are adequately approximated by straight lines. The differential molar isosteric heat of adsorption of n-pentane on the AUK adsorbent decreases of 58-46 kJ/mol in the whole region of micropore filling; this fact counts in favor of energetic heterogeneity in the micropores, which presumably appears in the process of thermochemical synthesis of the microporous carbon adsorbent of silicon carbide.

引用

页码：184 / 190

页数：6

共 50 条

[1] Adsorption of n-pentane on a microporous carbon adsorbent with a narrow pore size distribution
Shkolin, A. V.
Fomkin, A. A.
Sinitsyn, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2010, 46 (02) : 184 - 190
[2] Adsorption-Induced Deformation of AUK Microporous Carbon Adsorbent in Adsorption of n-Pentane
Shkolin, A. V.
Fomkin, A. A.
Sinitsyn, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (05) : 555 - 561
[3] Adsorption-induced deformation of AUK microporous carbon adsorbent in adsorption of n-pentane
A. V. Shkolin
A. A. Fomkin
V. A. Sinitsyn
Protection of Metals and Physical Chemistry of Surfaces , 2011, 47 : 555 - 561
[4] Methane adsorption on microporous carbon adsorbent with wide pore size distribution
A. A. Fomkin
I. E. Men’shchikov
A. A. Pribylov
V. V. Gur’yanov
A. V. Shkolin
D. S. Zaitsev
A. V. Tvardovskii
Colloid Journal, 2017, 79 : 144 - 151
[5] Methane adsorption on microporous carbon adsorbent with wide pore size distribution
Fomkin, A. A.
Men'shchikov, I. E.
Pribylov, A. A.
Gur'yanov, V. V.
Shkolin, A. V.
Zaitsev, D. S.
Tvardovskii, A. V.
COLLOID JOURNAL, 2017, 79 (01) : 144 - 151
[6] Methane Adsorption in Microporous Carbon Adsorbent with a Bimodal Pore Size Distribution
A. A. Fomkin
A. A. Pribylov
A. G. Tkachev
N. R. Memetov
A. V. Melezhik
A. E. Kucherova
I. N. Shubin
A. V. Shkolin
I. E. Men’shchikov
A. L. Pulin
S. A. Zhedulov
Protection of Metals and Physical Chemistry of Surfaces, 2020, 56 : 1 - 5
[7] Methane Adsorption in Microporous Carbon Adsorbent with a Bimodal Pore Size Distribution
Fomkin, A. A.
Pribylov, A. A.
Tkachev, A. G.
Memetov, N. R.
Melezhik, A. V.
Kucherova, A. E.
Shubin, I. N.
Shkolin, A. V.
Men'shchikov, I. E.
Pulin, A. L.
Zhedulov, S. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2020, 56 (01) : 1 - 5
[8] Ethane adsorption on microporous carbon adsorbent with a wide pore size distribution
Fomkin, A. A.
Pribylov, A. A.
Shkolin, A. V.
Men'shchikov, I. E.
Murdmaa, K. O.
Pulin, A. L.
RUSSIAN CHEMICAL BULLETIN, 2019, 68 (10) : 1838 - 1842
[9] Ethane adsorption on microporous carbon adsorbent with a wide pore size distribution
A. A. Fomkin
A. A. Pribylov
A. V. Shkolin
I. E. Men’shchikov
K. O. Murdmaa
A. L. Pulin
Russian Chemical Bulletin, 2019, 68 : 1838 - 1842
[10] Adsorption of n-Pentane on Mesoporous Silica and Adsorbent Deformation
Gor, Gennady Yu
Paris, Oskar
Prass, Johannes
Russo, Patricia A.
Ribeiro Carrott, M. Manuela L.
Neimark, Alexander V.
LANGMUIR, 2013, 29 (27) : 8601 - 8608

← 1 2 3 4 5 →