Effect of tetrabutyltin on the acidity and reducibility of platinum-tin alumina supported sol-gel catalysts

被引:0
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作者
T. López
R. Silva
V. Bertin
J. Sánchez
R. Gómez
机构
[1] Universidad Autónoma Metropolitana de Iztapalapa,Department of Chemistry
关键词
Platinum-tin catalysts; sol-gel catalysts; Lewis and Brönsted platinum-tin acidity; FTIR pyridine platinum-tin adsorption;
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摘要
Tin precursor effect in Pt−Sn/Al2O3 sol-gel catalysts has been studied. It is shown that catalysts prepared with tetrabutyltin allow a better reduction of platinum than catalysts prepared with tin tetrachloride and with tin tetra-tert-amyloxide. The solids prepared with tetrabutyltin are catalysts showing a high activity in isopropanol decomposition and cyclohexane dehydrogenation.
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页码:49 / 55
页数:6
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