A highly selective iodide electrode based on the bis(benzoin)-semiethylenediamine complex of mercury(II) as a carrier

被引：0
|
作者：
You-Qun Song
R. Yuan
M. Ying
Zhi-Qiang Li
Y.-Q. Chai
H. Cui
G.-L. Shen
Ru-Qin Yu
机构：
[1] Institute of Chemometrics and Chemical Sensing Technology,
[2] Chemistry and Chemical Engineering College,undefined
[3] Hunan University,undefined
[4] Changsha,undefined
[5] 410082,undefined
[6] China,undefined
来源：
Fresenius' Journal of Analytical Chemistry | 1998年 / 360卷
关键词：
Quartz; Mercury; Iodide; Linear Response; Quartz Crystal;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new PVC membrane electrode based on the bis(benzoin)-semiethylenediamine (BBSEA) complex of Hg(II) is described which exhibits excellent selectivity towards iodide, related to the unique interaction between the central Hg(II) and the iodide ion. The electrode has a linear response to iodide from 5 × 10–7 to 5 × 10–4 mol/L with a slope of 58 mV/dec.(20°C). The response characteristics were investigated in detail and the mechanism of the electrode was studied with AC impedance and quartz crystal microbalance (QCM) techniques. It can be used for iodide determinations in drug preparations.
引用
收藏
页码：47 / 51
页数：4
相关论文
共 50 条
  • [1] A highly selective iodide electrode based on the bis(benzoin)-semiethylenediamine complex of mercury(II) as a carrier
    Song, YQ
    Yuan, R
    Ying, M
    Li, ZQ
    Chai, YQ
    Cui, H
    Shen, GL
    Yu, RQ
    FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1998, 360 (01): : 47 - 51
  • [2] Bis-dimethylaminobenzaldehyde schiff-base cobalt(II) complex as a neutral carrier for a highly selective iodide electrode
    Dai, JY
    Chai, YQ
    Yuan, R
    Zhong, X
    Liu, Y
    Tang, DP
    ANALYTICAL SCIENCES, 2004, 20 (12) : 1661 - 1665
  • [3] Bis-dimethylaminobenzaldehyde Schiff-Base Cobalt(II) Complex as a Neutral Carrier for a Highly Selective Iodide Electrode
    Jianyuan Dai
    Yaqin Chai
    Ruo Yuan
    Xia Zhong
    Yan Liu
    Dianping Tang
    Analytical Sciences, 2004, 20 : 1661 - 1665
  • [4] Di(ethylxanthate) complex of cobalt(II) as neutral carrier for highly selective iodide electrode
    Lin, SQ
    Yuan, R
    TECHNICAL DIGEST OF THE SEVENTH INTERNATIONAL MEETING ON CHEMICAL SENSORS, 1998, : 792 - 794
  • [5] A highly sensitive PVC membrane iodide electrode based on complexes of mercury(II) as neutral carrier
    Chai, YQ
    Yuan, R
    Xu, L
    Xu, WJ
    Dai, JY
    Jiang, F
    ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2004, 380 (02) : 333 - 338
  • [6] A highly sensitive PVC membrane iodide electrode based on complexes of mercury(II) as neutral carrier
    Y. -Q. Chai
    R. Yuan
    L. Xu
    W. -J. Xu
    J. -Y. Dai
    F. Jiang
    Analytical and Bioanalytical Chemistry, 2004, 380 : 333 - 338
  • [7] Iodide Selective Electrode Based on Cobalt (II) Complex with Unsymmetrical Schiff Base as Neutral Carrier
    Xu Gang
    Yuan Ruo
    Chai Ya-Qin
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2008, 36 (08) : 1101 - 1104
  • [8] Highly selective thiocyanate electrode based on bis-bebzoin-semitriethylenetetraamine binuclear copper(II) complex as neutral carrier
    Yuan, R
    Wang, XL
    Xu, L
    Chai, YQ
    Sun, ZY
    Huang, XQ
    Li, QF
    Zhao, Q
    Zhou, L
    ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (08) : 717 - 721
  • [9] Construction of suitable iodide-selective electrode based on phenyl mercury (II)(2-mercaptobezothiozolate) carrier
    Shokrollahi, A.
    Ghaedi, M.
    Montazerozohori, M.
    Hosaini, O.
    Ghaedi, H.
    ANALYTICAL LETTERS, 2007, 40 (09) : 1714 - 1735
  • [10] Highly selective thiocyanate electrode based on bis-bebzion Schiff base binuclear copper(II) complex as neutral carrier
    Wu, X.
    Chai, Y. -Q.
    Yuan, R.
    Ye, G. -R.
    Zhou, W.
    ANALYTICAL LETTERS, 2008, 41 (05) : 890 - 901
12345