A New Molybdophosphate Constructed From {Mo2VO4(H2O)6}2+ and 1-Hydroxyethylidenediphosphonate

被引：0
|
作者：
Hua-Qiao Tan
Wei-Lin Chen
Ding Liu
En-Bo Wang
机构：
[1] Northeast Normal University,Key Laboratory of Polyoxometalates Science of Ministry of Education, Department of Chemistry
来源：
Journal of Cluster Science | 2010年 / 21卷
关键词：
Polymolybdate; 1-Hydroxyethylidenediphosphonate; Crystal structure; P NMR;
D O I：
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摘要：
A new molybdophosphate (NH4)8{Mo2VO4[(Mo2VIO6)CH3C(O)(PO3)2]2}·14H2O (1), has been synthesized by the reaction of {Mo2VO4(H2O)6}2+ fragments with 1-hydroxyethylidenediphosphonate (hedp HOC(CH3)(PO3H2)2), and it is characterized by 31P NMR, IR, UV, element analysis, TG and single-crystal X-ray analysis. The structure analysis reveals that the polyoxoanion can be described as two {(Mo2VIO6)(CH3C(O)(PO3)2} units connected by a {Mo2VO4}2+ moiety. In the structure, the six Mo atoms are arranged into a new “W-shaped” structure, which represents a new kind of molybdophosphate.
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页码：147 / 154
页数：7
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