Synthesis and structure of new dinuclear palladium complex containing no bridging ligands

被引：0
|
作者：
M. O. Talismanova
I. G. Fomina
A. A. Sidorov
G. G. Aleksandrov
N. T. Berberova
A. O. Okhlobystin
E. V. Shinkar"
I. F. Golovaneva
I. L. Eremenko
I. I. Moiseev
机构：
[1] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
[2] Astrakhan State Technical University,undefined
来源：
Russian Chemical Bulletin | 2003年 / 52卷
关键词：
-phenylenediamine; palladium complexes; semiquinonediimine complexes; electrochemical properties; X-ray diffraction analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Oxidation of the mononuclear semiquinonediimine complex [(NPh)(NH)C6H4]2Pd with silver trifluoromethanesulfonate afforded the diamagnetic dinuclear dicationic palladium complex {[(NPh)(NH)C6H4]2Pd}2(O3SCF3)2 with a Pd...Pd distance of 3.267(1) Å. The complex was structurally characterized, and its spectroscopic and electrochemical properties were studied.
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页码：2701 / 2706
页数：5
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