Characterization of anatase nanocrystal-precipitated coatings from (100 - x)SiO2·xTiO2 gel films via the sol-gel process with boiling hot water treatment

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作者
Atsunori Matsuda
Tatsuo Matoda
Toshihiro Kogure
Kiyoharu Tadanaga
Tsutomu Minami
Masahiro Tatsumisago
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[1] Toyohashi University of Technology,Department of Materials Science
[2] Osaka Prefecture University,Department of Applied Materials Science, Graduate School of Engineering
[3] The University of Tokyo,Department of Earth and Planetary Sciences, Graduate School of Science
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摘要
Considerable amounts of anatase nanocrystals were formed on the (100 - x)SiO2·xTiO2 coatings with x of 16.5 and 25 mol% with boiling water treatment, whereas the formation of anatase nanocrystals was not clearly observed for the coatings with x of 50 and 75 mol%. Despite the lower TiO2 content, the coatings with x of 16.5 and 25 mol% showed higher concentration of Si–O–Ti bonds among the coatings. Thus, the hydrolysis of Si–O–Ti bonds and resultant sites should facilitate the nucleation and growth of anatase nanocrystals. High transparency, high photocatalytic activity, and superhydrophilicity were demonstrated for the anatase nanocrystals-precipitated coatings.
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页码:256 / 263
页数:7
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