Effect of the cooling rate on the phase composition of crystallized CdGeAs2 melts

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作者：
A. N. Aronov
S. F. Marenkin
I. V. Fedorchenko
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] National University of Science and Technology “Moscow Institute of Steel and Alloys”,undefined
来源：
Russian Journal of Inorganic Chemistry | 2017年 / 62卷
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摘要：
The formation of metastable Cd3Ge2As4 was established using a set of physicochemical analysis methods. The annealing of this compound at temperatures ≥450°C was shown to lead to the formation of the stable binary eutectic Cd3As2–СdGeAs2 and ternary eutectic Cd3As2–СdGeAs2–CdAs2 with the following composition (at %): Cd, 42.20; Ge, 15.69; As, 42.11; and Cd, 42.70; Ge, 15.06; As, 42.24, respectively.
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页码：1645 / 1651
页数：6
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