Diffusion Mass Transfer in Miscible Oil Recovery: Visual Experiments and Simulation

Co-and counter-current type transfers due to diffusion and -free- convection caused by the buoyant forces between fracture and matrix were studied experimentally using 2-D glass-bead models. Mineral oil and kerosene were used as the displaced phase. The model saturated with oil was exposed to solvent phase (pentane) under static conditions (no flow in fracture) to mimic matrix-fracture interaction during gas or liquid solvent injection in naturally fractured reservoirs. Displacement fronts and patterns were analyzed and quantified using fractal techniques to obtain correlations between the fractal properties and displacement type. Displacements resulted in a mixture of bulk diffusion and -free- convection mainly depending on the interaction type (co- or counter-current), oil type, and displacement direction (horizontal and vertical). Conditions yielding different types of displacement patterns were identified. Finally, a stochastic model that was inspired from invasion percolation and diffusion limited aggregation algorithms was developed for the horizontal displacement cases. The experimental observations were matched to the displacement patterns obtained through the stochastic modeling.