Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)

Differential scanning calorimetry and thermogravimetry are used to study the thermolysis of following complexes: (Acac)2Sn(N3)Cl (1); (Acac)2SnCl2 (2); (CO)5MSn(Acac)2 with M = Cr (3) or W ((4)), (CO)5MSnCl2(thf) with M = Cr (5), Mo (6), or W (7)), (CH3)4N(CO)5MSnCl3 with M = Mo (8) or W ((9)), (CO)2MnCpSnCl2(thf) (10)); and (CO)5MSn(SCN)2 with M = Cr (11) or W (12). The phase composition of the solid thermolysis products of compounds 1–5 and 7–12 is determined by X-ray powder diffraction. Thermolysis schemes are suggested.