Anilido-imine zinc complexes: Efficient catalysts for ring-opening polymerization of L-lactide

被引：0
|
作者：
Wei Yao
Ning Cui
Ying-zhao Xue
Tian-tian Liu
Yan Wang
机构：
[1] University of Jinan,School of Resources and Environment
来源：
Chemical Research in Chinese Universities | 2013年 / 29卷
关键词：
Anilido-imine ligand; Zinc complex; Ring-opening polymerization; Lactide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of anilido-imine zinc complexes ortho-C6H4(CH=NAr)(NAr)ZnEt[Ar=2,6-Me2C6H3(2a); Ar=2,6-Et2C6H3(2b)] was synthesized, characterized and used as catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol. The effects of the structures of catalysts and reaction conditions on the reactivity were investigated. The polymerization of L-lactide initiated by each of these complexes was found to take place with a controlled manner.
引用
收藏
页码：48 / 50
页数：2
相关论文
共 50 条
  • [1] Anilido-imine Zinc Complexes: Efficient Catalysts for Ring-opening Polymerization of L-Lactide
    Yao Wei
    Cui Ning
    Xue Ying-zhao
    Liu Tian-tian
    Wang Yan
    [J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2013, 29 (01) : 48 - 50
  • [2] Tridentate Anilido-Aldimine Magnesium and Zinc Complexes as Efficient Catalysts for Ring-Opening Polymerization of ε-Caprolactone and L-Lactide
    Tsai, Yueh-Hsuan
    Lin, Chia-Her
    Lin, Chu-Chieh
    Ko, Bao-Tsan
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (19) : 4927 - 4936
  • [3] Synthesis and Structures of Tridentate Ketoiminate Zinc Complexes That Act As L-Lactide Ring-Opening Polymerization Catalysts
    Roberts, Courtney C.
    Barnett, Brandon R.
    Green, David B.
    Fritsch, Joseph M.
    [J]. ORGANOMETALLICS, 2012, 31 (11) : 4133 - 4141
  • [4] Zinc Complexes Containing Coumarin-Derived Anilido-Aldimine Ligands as Catalysts for Ring Opening Polymerization of L-Lactide
    Chen, Chi-Tien
    Wang, Min-Chian
    Huang, Tzu-Lun
    [J]. MOLECULES, 2015, 20 (04) : 5313 - 5328
  • [5] Ring-opening polymerization of L-lactide catalyzed by calcium complexes
    Hsiao, Mon-Wei
    Lin, Chu-Chieh
    [J]. DALTON TRANSACTIONS, 2013, 42 (06) : 2041 - 2051
  • [6] Investigation of Silyl-Amide Complexes as Catalysts for the Ring-Opening Polymerization of L-Lactide
    Lee, Chanwoo
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (13) : 4092 - 4096
  • [7] Magnesium Pyrazolyl-Indolyl Complexes as Catalysts for Ring-Opening Polymerization of L-Lactide
    Chen, Chi-Tien
    Lin, Deng-Hao
    Peng, Kuo-Fu
    [J]. POLYMERS, 2015, 7 (10): : 1954 - 1964
  • [8] Ring-opening polymerization of ε-caprolactone and L-lactide using ethyl salicylate-bearing zinc complexes as catalysts
    Su, Rou-Rong
    Ganta, Prasanna Kumar
    Cheng, Che-An
    Hu, Yu-Ting
    Chang, Yung-Chi
    Chang, Chun-Juei
    Ding, Shangwu
    Chen, Hsuan-Ying
    Wu, Kuo-Hui
    [J]. MOLECULAR CATALYSIS, 2023, 537
  • [9] Synthesis, characterization and catalytic activity of magnesium and zinc aminophenoxide complexes: Catalysts for ring-opening polymerization of L-lactide
    Chuang, Hui-Ju
    Weng, Shi-Feng
    Chang, Chia-Chih
    Lin, Chu-Chieh
    Chen, Hsuan-Ying
    [J]. DALTON TRANSACTIONS, 2011, 40 (37) : 9601 - 9607
  • [10] Catalysts for the ring-opening polymerization of ε-caprolactone and L-lactide and the mechanistic study
    Yu, TL
    Wu, CC
    Chen, CC
    Huang, BH
    Wu, JC
    Lin, CC
    [J]. POLYMER, 2005, 46 (16) : 5909 - 5917
12345